The reality star, 26, looked in good spirits as she wrapped her arms around her partner, 21, as they made their way to a waiting car.
Holly, 40, exuded elegance in a strapless light pink gown which featured a ruffled neckline and figure-hugging design.
She completed the look with white heels and wore her blonde tresses in loose waves over her shoulders while opting for a glamorous makeup look.
Chloe opted for a dark blue sleeveless gown which featured a teal patterned train while she styled her locks into a ponytail.
Toby looked dapper in a black velvet blazer and matching trousers as he helped his girlfriend out of the venue.
Party: Love Island’s Chloe Burrows enjoyed a raucous night out at the bash as she was carried out of the venue barefoot by her boyfriend Toby Aromolaran
Meanwhile, Vogue Williams effortlessly turned heads in a figure-hugging emerald gown with a cut out along the sides.
The garment also featured a leg split while the star added height to her frame with a pair of gold heels.
Vogue was all smiles as she departed the awards show alongside husband Spencer Matthews who sported a white blazer and a matching shirt with black trousers.
Emily Atack put on a very stylish display in a dark green skirt with a high leg split and a matching crop top.
Couple: Vogue Williams was all smiles as she departed the awards show alongside husband Spencer Matthews
Smooch: Lottie Tomlinson and her boyfriend Lewis Burton put on a loved-up display as they made their departure from the awards
The Celebrity Juice star added height to her frame with a pair of black heels while she let her blonde locks fall loose down her shoulders.
Comedian Katherine Ryan and reality star Vicky Pattison appeared in good spirits as they were seen catching up on their way out of the venue.
Lottie Tomlinson and her boyfriend Lewis Burton put on a loved-up display as they made their departure from the awards.
The couple were seen sharing a kiss in their taxi, with Lottie looking sensational in a black long-sleeved mini dress.
Flawless: Emily blew a kiss as she left the bash alongside a group of friends
Cosy: Love Island winners Millie Court and Liam Riordan left the venue holding hands
Finalists: Chloe and Toby finished as runners-up on this year’s series of Love Island
Millie Court flashed her décolletage in a plunging brown cardigan while Liam Reardon donned a white T-shirt featuring a Nike motif.
Simon Cowell cut a dapper figure in a black suit as he departed the awards alongside his longtime partner Lauren Silverman.
Lauren looked incredible in a pale pink sleeveless gown with a diamond collar while she also sported a pair of heels and carried a matching clutch bag.
Pride of Britain sees a night of ‘extraordinary stories of bravery, selflessness and phenomenal fundraising feats’ as well as a plethora of astounding surprises, laugh out loud situations and emotional moments as the nation comes together to honour the achievements of truly inspirational people.
Attendees: Charlie Brooks donned a black sleeveless jumpsuit while Saffron Barker opted for an emerald off the shoulder gown
Romance: Lottie and Lewis wrapped their arms around each other as they made their way home
Among the winners were quadruple amputee Harmonie-Rose Allen who wins the Child of Courage Award for inspiring the nation with her courage and unbreakable spirit.
While the Lifetime Achievement Award goes to campaigner Rosemary Cox, who set up the first Organ Donor Register in the UK, helping save thousands of lives.
Campaigning sisters Amy and Ella Meek, 18 and 16, have been named Pride of Britain’s first ever Environmental Champions for setting up a charity to help fight the global scourge of plastic pollution.
Meanwhile, this year’s Special Recognition Award went to Gee Walker, who forgave her son’s killers and devoted her life to promoting racial harmony in his memory.
Speaking about the ceremony, Carol said: ‘My favourite part of the Awards are the winners and how happy they are that they’re being celebrated.
‘These incredible people make you want to be a better person. And even though everyone says how much it makes them cry, it is a celebration too of all the truly extraordinary things they have done.’
Ashley Banjo said: ‘I have so much respect and admiration for all of the winners’ and I can’t wait to meet them, see the look on their faces as they are surprised and celebrated and to experience this really special moment with them.’
While Debbie Crosbie, Chief Executive Officer of award partner TSB adds: ‘I have been bowled over by the bravery, courage and determination of all the winners.
‘Helping people in our local communities is at the heart of what we do at TSB – that’s why we are especially proud to sponsor the TSB Community Hero Award. It is truly humbling to see the extraordinary things people have done to make a difference and support those most in need in their communities.’
Nominated by the public, the winners are from all walks of life, of all ages, and from all over the country.
Since the first ceremony in 1999, royalty, prime ministers, and hundreds of leading figures from showbusiness, sport, politics and the arts have all taken part.
The awards attract an audience of around five million viewers every year in a primetime slot on ITV – making it the highest rated awards show of its kind on British television.
Due to COVID-19 restrictions, 2020’s ceremony featured prerecorded segments of recipients receiving their awards at home, while a host of big names headed to The Royal Hospital Chelsea to film links ahead of the show.
As the awards aired on ITV, landmarks across London, including the London Eye, BT Tower and County Hall, turned red, white and blue in celebration of the winners.
Marcus Rashford and the late Captain Sir Tom Moore were among those honoured in the ceremony, which awarded the remarkable achievements of Brits who have selflessly contributed the the nation and the world.
PRIDE OF BRITAIN AWARDS 2021: THE WINNERS
LIFETIME ACHIEVEMENT – Rosemary Cox, 82, Wolverhampton
SPECIAL RECOGNITION – Rob Allen, 34, Northampton
THIS MORNING EMERGENCY SERVIVES AWARD – Stephen Warton, 53, Cumbria
GOOD MORNING BRITAIN YOUNG FUNDRAISER – Hughie Higginson, 10, and Freddie Xavi, 11, Lancashire
CHILD OF COURAGE – Harmonie-Rose Allen, 7, Bath
SPIRIT OF ADVENTURE – Max Woosey, 11, North Devon
SPECIAL RECOGNITION – Gee Walker, 67, Liverpool
ENVIRONMENTAL CHAMPION – Amy and Ella Meek, 18 and 16, Nottingham
PRINCE’S TRUST YOUNG ACHIEVER – Hassan Alkhawam, 23, Northern Ireland